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p-茴香胺,p-Anisidine;≥99.0% [对茴香胺]

别名:4-氨基苯甲醚;4-甲氧基苯胺;对氨基苯甲醚;对甲氧基苯胺;4-Aminoanisole;4-Methoxyaniline

CAS号 104-94-9 线性分子式 CH3OC6H4NH2 分子量 123.15 Beilstein/REAXYS Number 471556 MDL number MFCD00007864 PubChem Substance ID 24891372 NACRES NA.22
货号(SKU): A88255
CAS号: 104-94-9
MDL号: MFCD00007864
增值税发票 √ 免费货运 [顺丰 联邦] √
$40.25

产品描述

Application

p-Anisidine can undergo aerobic oxidation in the presence of gold catalysts to form aromatic azo compounds.[1]
p-Anisidine can be used:
•  In the diastereoselective and enantioselective synthesis of CF3-substituted azoridines catalyzed by a chiral Bronsted acid.[2]
•  To prepare 4-organoselenium-quinolines through multi-component Povarov reaction with ethyl glyoxylate and ethynyl(phenyl)selane, catalyzed by Yb(OTf)3.[3]
•  As a starting material to synthesize 3-fluoro-6-methoxyquinoline in two steps.[4],
•  To prepare N-PMP protected α-aminopropargylphosphonates by reacting with terminal alkynes and diethyl formylphosphonate hydrate using silver(I) triflate as a catalyst.[5]
在金催化剂存在下,对茴香胺可进行好氧氧化,形成芳族偶氮化合物。[1]
对茴香胺可用于:
•在手性布朗斯台德酸催化下,CF3取代的偶氮啶的非对映选择性和对映选择性合成[2]。
•在Yb(OTf)3的催化下,通过与乙醛酸乙酯和乙炔基(苯基)硒烷的多组分Povarov反应制备4-有机硒代喹啉。[3]
•作为分两步合成3-氟-6-甲氧基喹啉的原料。[4],
•通过使用三氟甲磺酸银(I)作为催化剂,与末端炔烃和二乙基甲酰基膦酸酯水合物反应,制备N-PMP保护的α-氨基炔丙基膦酸酯[5]。

包装

1 kg in glass bottle

5, 100, 250 g in glass bottle

性质

Quality Level200
assay99%
autoignition temp.959 °F
bp240-243 °C (lit.)
mp56-59 °C (lit.)
SMILES stringCOc1ccc(N)cc1
InChI1S/C7H9NO/c1-9-7-4-2-6(8)3-5-7/h2-5H,8H2,1H3
InChI keyBHAAPTBBJKJZER-UHFFFAOYSA-N


安全信息

信号词
Danger
危害码 (欧洲) T+,N
风险声明 (欧洲) 45-26/27/28-33-50
安全声明 (欧洲) 53-28-36/37-45-61
RIDADR UN2811 - class 6.1 - PG 3 - EHS - RQ - Toxic solids, organic, n.o.s. HI: all
WGK德国 WGK 3
闪点(华氏) 251.6 °F - closed cup
闪点(摄氏) 122 °C - closed cup
商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 190 | 欧洲Eur. ≥ 66 | 東京Tokyo ≥ 82 | 香港与北京 ≥ 55