N-烯丙基-N,N-双(三甲基甲硅烷基)胺，N-Allyl-N,N-bis(trimethylsilyl)amine；97%

图片 N-烯丙基-N,N-双(三甲基甲硅烷基)胺，N-Allyl-N,N-bis(trimethylsilyl)amine；97%
线性分子式: CH2=CHCH2NH[Si(CH3)3]2 CAS号: 7688-51-9 分子量: 201.46 EC 号: 231-699-2 MDL编号: MFCD00545193 PubChem化学物质编号: 24880960 NACRES: NA.22
制造商品牌: 西格玛 Sigma-Aldrich
货号（SKU）: 578932
CAS号: 7688-51-9
MDL号: MFCD00545193
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说明

应用

N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare:
  • Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions.[1]
  • Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride.[1]
  • Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.[1]
AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction.[1] It may be also used as an electrolyte additive.[2]
 
 

属性

检测方案

97%

形式

liquid

折射率

n20/D 1.440 (lit.)

bp

72 °C/15 mmHg (lit.)

密度

0.816 g/mL at 25 °C (lit.)

SMILES string

C[Si](C)(C)N(CC=C)[Si](C)(C)C

InChI

1S/C9H23NSi2/c1-8-9-10(11(2,3)4)12(5,6)7/h8H,1,9H2,2-7H3

InChI key

CVNCFZIIZGNVFD-UHFFFAOYSA-N

 

安全信息

象形图

FlameExclamation mark
GHS02,GHS07

警示用语：

Warning

危险分类

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(F)

109.0 °F - closed cup

闪点(C)

42.78 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 20 | 欧洲Eur. ≥ 16 | 東京Tokyo ≥ 5 | 香港与北京 ≥ 20
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