COi8DFIC [O6T-4F];≥98%

别名:NFA146, PCE146, O6T-4F, 2,2′-[[4,4,11,11-tetrakis(4-hexylphenyl)-4,11-dihydrothieno[2′,3′:4,5]thieno[2,3-d]thieno[2′′′′,3′′′′:4′′′,5′′′]thieno[2′′′,3′′′:4′′,5′′]pyrano[2′′,3′′:4′,5′]thieno[2′,3′:4,5]thieno[3,2-b]pyran-2,9-diyl]bis[methylidyne(5,6-difluoro

Empirical Formula (Hill Notation): C94H76F4N4O4S6 CAS号: 2184266-44-0 分子量: 1594.02
制造商品牌: 西格玛 Sigma-Aldrich
货号(SKU): 906379
CAS号: 2184266-44-0
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¥5,298.51

说明

一般描述

COi8DFIC or O6T-4F is a highly efficient, n-type, low-bandgap nonfullerene acceptor with strong NIR absorption.
In a recent study, COi8DFIC or O6T-4F was selected in a Tandem cell by computer assited design and gave a record PCE of 17.3∃% for fabricated organic solar cells.
COi8DFIC or O6T-4F is frequently selected to blend with a narrow-bandgap donor material and another narrow bandgap acceptor material to fabricate ternary organic solar cells. The PTB7-Th:COi8DFIC:PC71BM ternary cells offered a PCE of 14.08%. By further adopting a post-annealing process, an outstanding PCE of 14.62% can be achieved. Furthermore, the device utilizing COi8DFIC exhibited a good thermal stability with PCEs over 13.5% in a wide temperature range (70–160 °C).
 

应用

COi8DFIC or O6T-4F is a highly efficient, n-type, low-bandgap nonfullerene acceptor with strong NIR absorption
In a recent study, COi8DFIC or O6T-4F was selected in a Tandem cell by computer assited design and gave a record PCE of 17.3% for fabricated organic solar cells.

Tandem Cell Device performance:
ITO/ZnO/PFN-Br/PBDB-T:F-M/M-PEDOT/ZnO/PTB7- Th:O6T-4F:PC71BM/MoO3/Ag
Voc=1.642 V
Jsc=14.35 mA/cm2
FF=73.7%
PCE=17.3%
COi8DFIC or O6T-4F is frequently selected to blend with a narrow-bandgap donor material and another narrow bandgap acceptor material to fabricate ternary organic solar cells. The PTB7-Th:COi8DFIC:PC71BM ternary cells offered a PCE of 14.08%. By further adopting a post-annealing process, an outstanding PCE of 14.62% can be achieved. Furthermore, the device utilizing COi8DFIC exhibited a good thermal stability with PCEs over 13.5% in a wide temperature range (70-160 °C).

Device structure:
ITO/ZnO/PTB7-Th:COi8DFIC:PC71BM/MoO3/Ag
  • Before annealing
Voc=0.702 V
Jsc=27.74 mA/cm2
FF=0.701
PCE=13.65%

  • After annealing at 80°C
Voc=0.727 V
Jsc=27.39 mA/cm2
FF=0.734
PCE=14.62%
COi8DFIC, an efficient non-fullerene acceptor material, has a strong near-infrared range (NIR) light absorption. It can be used as an n-type small molecule acceptor material for the fabrication of polymeric solar cells.
 
 

属性

描述

Band gap: 1.62 eV

测定

≥98%

形式

solid

溶解性

soluble (chloroform, CB and ODCB)

轨道能量

HOMO -5.5 eV 
LUMO -3.88 eV 

 

安全信息

储存分类代码

13 - Non Combustible Solids

WGK

WGK 3

商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 50 | 欧洲Eur. ≥ 12 | 東京Tokyo ≥ 20 | 香港与北京 ≥ 50