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2,2′-双(二苯基膦)-1,1′-联萘 [rac-BINAP],2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl;97%

别名:(±)-2,2′-双(二苯基膦)-1,1′-联萘;[1,1′-联萘]-2,2′-双二苯膦;(±)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene, (±)-BINAP, 2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene, [1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine]

CAS号 98327-87-8 线性分子式 [(C6H5)2PC10H6-]2 分子量 622.67 Beilstein/REAXYS Number 5321443 MDL number MFCD00010805 PubChem Substance ID 24871738 NACRES NA.22
货号(SKU): 481084
CAS号: 98327-87-8
MDL号: MFCD00010805
增值税发票 √ 免费货运 [顺丰 联邦] √
€58.21

产品描述

General description

外消旋型 BINAP。[1]

包装

5, 25, 100, 500 g in glass bottle

Application

钯催化芳基胺偶联反应的配体,用于制备去甲基硫代秋水仙碱。[2]可与 Cu(II) 联合使用催化芳基磺酰胺加成反应生成苯乙烯和烯烃。[3]亦可用于钯催化的三联吡啶胺化反应。[4]

性质

Quality Level200
assay97%
reaction suitabilityreagent type: catalyst
reaction type: Cross Couplings
reagent type: ligand
reaction type: Acylations
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: C-C Bond Formation
reagent type: ligand
reaction type: Decarboxylations
reagent type: ligand
reaction type: Stille Coupling
mp283-286 °C (lit.)
functional groupphosphine
InChI1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H
InChI keyMUALRAIOVNYAIW-UHFFFAOYSA-N


安全信息

个人防护装备 EyeshieldsGlovestype N95 (US)
RIDADR NONH for all modes of transport
WGK德国 WGK 3
商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 88 | 欧洲Eur. ≥ 126 | 東京Tokyo ≥ 46 | 香港与北京 ≥ 62
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