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2-(二苯基膦)对苯二甲酸 1-甲基 4-五氟苯基二酯,2-(Diphenylphosphino)terephthalic acid 1-methyl 4-pentafluorophenyl diester;97%

别名:1-甲基-4-(五氟苯基)-2-(二苯基膦)-1,4-苯二羧酸酯;1-Methyl-4-(pentafluorophenyl)-2-(diphenylphosphino)-1,4-benzenedicarboxylate

Empirical Formula (Hill Notation): C27H16F5O4P 分子量: 530.38 MDL编号: MFCD09265125 PubChem化学物质编号: 24885463 NACRES: NA.22
制造商品牌: 西格玛 Sigma-Aldrich
货号(SKU): 679011
MDL号: MFCD09265125
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¥1,938.31

说明

应用

  • Staudinger ligation reagent for the conjugation of amine and azide containing compounds or biomolecules.
  • The amine functionalized molecule first reacts with the phosphine through the activated pentafluorophenyl ester.The azide-molecule is then reacted with the newly labeled phosphine to form the iminophosphorane, and the aza-ylide is subsequently captured by the methyl ester to yield the covalent conjugated product.[1]
2-(Diphenylphosphino)terephthalic acid 1-methyl 4-pentafluorophenyl diester Staudinger Ligation Probe and Target
The Staudinger Ligation: A High-Yield, Chemoselective, and Mild Synthetic Method
 
 

属性

质量水平

测定

97%

形式

solid

reaction suitability

reaction type: click chemistry

mp

109-111 °C

储存温度

−20°C

SMILES string

COC(=O)c1ccc(cc1P(c2ccccc2)c3ccccc3)C(=O)Oc4c(F)c(F)c(F)c(F)c4F

InChI

1S/C27H16F5O4P/c1-35-27(34)18-13-12-15(26(33)36-25-23(31)21(29)20(28)22(30)24(25)32)14-19(18)37(16-8-4-2-5-9-16)17-10-6-3-7-11-17/h2-14H,1H3

InChI key

OURNVXDJALDDIG-UHFFFAOYSA-N

 

安全信息

储存分类代码

13 - Non Combustible Solids

WGK

WGK 3

商品规格
属性名称属性值
储存温度 Storage temp.-20°C低温冷冻
全球实时库存 Availability √美国St. Louis ≥ 55 | 欧洲Eur. ≥ 16 | 東京Tokyo ≥ 8 | 香港与北京 ≥ 10