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(1S)-(-)-2,10-樟脑磺内酰胺,(1S)-(−)-2,10-Camphorsultam;98%

别名:(-)-10,2-樟脑磺内酰胺;(-)-exo-10,2-莰烷磺内酰胺;(1S,5R)-10,10-二甲基-3-硫杂-4-氮杂三环[5.2.1.01,5]癸烷-3,3-二氧化物;[3aS-(3aα,6α,7aβ)]-六氢-8,8-二甲基-3H-3a,6-亚甲基-2,1-苯并异噻唑基-2,2-二氧化物;(−)-10,2-Camphorsultam, (−)-exo-10,2-Bornanesultam, (1S,5R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]decane 3,3-dioxide, [3aS-(3aα,6α,7aβ)]-hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole-2,2-dioxide

CAS号 94594-90-8 经验分子式(希尔表示法) C10H17NO2S 分子量 215.31 Beilstein/REAXYS Number 83811 MDL number MFCD00066271 PubChem Substance ID 24857980 NACRES NA.22
制造商品牌: 西格玛 Sigma-Aldrich
货号(SKU): 298352
CAS号: 94594-90-8
MDL号: MFCD00066271
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¥632.00

产品描述

General description

(1S,2R,4R)-(−)-2,10-Camphorsultam may be employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids.[3]

Application

(1S)-(−)-2,10-Camphorsultam may be used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine.[1] It may be used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones.[2]

包装

5 g in glass bottle

性质

Quality Level  200
assay  98%
optical activity  [α]19/D −32°, c = 5 in chloroform
mp  181-183 °C (lit.)
SMILES string  [H][C@@]12CC[C@]3(CS(=O)(=O)N[C@@H]3C1)C2(C)C
InChI  1S/C10H17NO2S/c1-9(2)7-3-4-10(9)6-14(12,13)11-8(10)5-7/h7-8,11H,3-6H2,1-2H3/t7-,8-,10-/m1/s1
InChI key  DPJYJNYYDJOJNO-NQMVMOMDSA-N


安全信息

个人防护装备 dust mask type N95 (US)EyeshieldsGloves
危害码 (欧洲) Xi
风险声明 (欧洲) 36/37/38
安全声明 (欧洲) 26
RIDADR NONH for all modes of transport
WGK德国 WGK 3
商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 33 | 欧洲Eur. ≥ 27 | 東京Tokyo ≥ 9 | 香港与北京 ≥ 16