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[1,1′-双(二苯基膦)二茂铁]二氯化钯(II),[1,1′-Bis(diphenylphosphino)ferrocene] dichloropalladium(II) [Pd(dppf)Cl2]

别名: Pd(dppf)Cl2 线性分子式: (C17H14P)2Fe . PdCl2 CAS号: 72287-26-4
制造商品牌: 西格玛 Sigma-Aldrich
货号(SKU): 919780
CAS号: 72287-26-4
MDL号: MFCD00015757
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¥1,370.70

说明

应用

Catalyst for C-C and C-N coupling reaction.
Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:
  • Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.[1]
  • Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.[2]
  • Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.[3]
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
 
 
 

属性

形式

solid

质量水平

组成

~ 4 wt.% loading of catalyst

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

InChI

1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q2*-1;;;2*+2/p-2

InChI key

NXQGGXCHGDYOHB-UHFFFAOYSA-L

 

安全信息

象形图

Health hazard

警示用语:

Danger

危险声明

危险分类

Carc. 1B Inhalation

储存分类代码

6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 50 | 欧洲Eur. ≥ 12 | 東京Tokyo ≥ 20 | 香港与北京 ≥ 50
商品标签 [tags]