对羟基联苯,4-Phenylphenol [4-HBP];purified by sublimation, 99%

别名:4-羟基联苯;4-Hydroxybiphenyl; 线性分子式: C6H5C6H4OH CAS号: 92-69-3 分子量: 170.21 Beilstein/REAXYS Number: 1907452 EC 号: 202-179-2 MDL编号: MFCD00002347 PubChem化学物质编号: 24866580 NACRES: NA.22
制造商品牌: 西格玛 Sigma-Aldrich
货号(SKU): 424625
CAS号: 92-69-3
MDL号: MFCD00002347
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¥513.07

说明

4-苯基苯酚(4-羟基联苯,4-HBP)是一种联芳基化合物,是一种弱酸性的4-芳基苯酚。 已经报道了对其晶体结构的研究。 据报道,它通过 Pd(0) 催化的 Suzuki 交叉偶联反应在水中快速、绿色合成。 已使用燃烧量热法评估了 4-苯基苯酚的标准摩尔形成焓。 已经研究了吸附在滤纸上的 4-苯基苯酚的固体基质发光特性。 使用酵母双杂交试验进行的一项研究表明它显示出雌激素活性。

一般描述

4-Phenylphenol (4-hydroxybiphenyl, 4-HBP), a biaryl compound, is a weakly acidic 4-arylphenol. A study on its crystalline structure has been reported. Its rapid, green synthesis via a Pd(0)-catalyzed Suzuki cross-coupling reaction in water has been reported. The standard molar enthalpy of formation of 4-phenylphenol has been evaluated using combustion calorimetry. The solid-matrix luminescence properties for 4-phenylphenol adsorbed on filter paper has been investigated. A study conducted using the yeast two-hybrid assay suggests that it shows estrogenic activity.
 

应用

4-Phenylphenol may be used in the following studies:
  • As a reactant in the synthesis of new azobenzene sulfonic acid dopants by diazotized coupling reaction with sulphanilic acid diazonium salt.
  • As a starting material in the synthesis of 2,6-poly(4-phenylphenol).
  • As a ligand in the synthesis of aluminum (III) bis(2-methyl-8-quninolinato)-4-phenylphenolate (BAlq).

包装

1 g in poly bottle
 
 

属性

质量水平

100

测定

99%

纯化方式

sublimation

bp

321 °C (lit.)

mp

164-166 °C (lit.)

溶解性

water: soluble 0.7 g/L at 20 °C

SMILES string

Oc1ccc(cc1)-c2ccccc2

InChI

1S/C12H10O/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9,13H

InChI key

YXVFYQXJAXKLAK-UHFFFAOYSA-N

Gene Information

rat ... Ar(24208)

 

安全信息

象形图

Exclamation markEnvironment

警示用语:

Warning

危险声明

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 20 | 欧洲Eur. ≥ 16 | 東京Tokyo ≥ 5 | 香港与北京 ≥ 20