Potassium bromide is widely used in optics because KBr has a low refractive index and a wide spectral range into the infrared with nearly no absorption. As a result, KBr is widely used as infrared optical windows, as infrared beamsplitters, and as substrates for interferometers. Commonly KBr is used in transmission infrared spectroscopy as a media for powder samples. The KBr and powder are ground together and pressed, using a die, into a thin disc under vacuum. The disc suspends the sample without contributing to the transmitted signal. Potassium bromide has also been used in synthesis, commonly as a source of bromide ions. For example, double displacement of KBr and bismuth nitrate yielded nanosheets of bismuth oxybromide.
[1] [2] Solutions of KBr have also been found to be useful shape-control agents or crystal-habit modifiers in formation of metal nanocrystals, including palladium nanorods
[3] and bimetallic platinum-paladium nanocrystals.
[4] [5] KBr is a common source of bromide ions used as nucleophiles in organic chemistry.