三甲基苯基氢氧化铵溶液，Trimethylphenylammonium hydroxide solution [TMAH]；~25% in H2O (1.68 M)

图片 三甲基苯基氢氧化铵溶液，Trimethylphenylammonium hydroxide solution [TMAH]；~25% in H2O (1.68 M)
别名：TMAH溶液；苯基三甲基氢氧化铵；Phenyltrimethylammonium hydroxide；TMAH

线性分子式: (CH3)3N(OH)C6H5 CAS号: 1899-02-1 分子量: 153.22 Beilstein: 3917033 MDL编号: MFCD00041899 PubChem化学物质编号: 57652783 NACRES: NA.22
制造商品牌: 西格玛 Sigma-Aldrich
货号（SKU）: 79267
CAS号: 1899-02-1
MDL号: MFCD00041899
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说明

一般描述

Trimethylphenylammonium hydroxide solution (TMPAH) is a quaternary ammonium compound that is commonly used as a strong base in organic synthesis. It is also used as a deprotecting agent for the removal of t-butoxycarbonyl (Boc) groups from amino acids or peptides and benzyl protecting groups from alcohols or amines.
 

应用

Trimethylphenylammonium hydroxide solution can be used to initiate the polymerization of the monomer 1,8-dihydroxymethyl-1,3,5,7-octatetrayne (DHOT) for the preparation of polymer nanospheres. It is also used as a base in the synthesis of alkyl 3-nitroacrylates via aldol reaction with nitroacetaldehyde or nitroacetone.
 
 

属性

形式

liquid

浓度

~25% in H2O (1.68 M)

折射率

n20/D 1.395

SMILES string

[OH-].C[N+](C)(C)c1ccccc1

InChI

1S/C9H14N.H2O/c1-10(2,3)9-7-5-4-6-8-9;/h4-8H,1-3H3;1H2/q+1;/p-1

InChI key

HADKRTWCOYPCPH-UHFFFAOYSA-M

 

安全信息

象形图

Corrosion
GHS05

警示用语：

Danger

危险声明

H314

危险分类

Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 10 | 欧洲Eur. ≥ 8 | 東京Tokyo ≥ 6 | 香港与北京 ≥ 60
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