三氟甲磺酸钙，Calcium trifluoromethanesulfonate；99.9%

图片 三氟甲磺酸钙，Calcium trifluoromethanesulfonate；99.9%
别名：三氟甲烷磺酸钙；Calcium triflate； 线性分子式: (CF3SO3)2Ca CAS号: 55120-75-7 分子量: 338.22 MDL编号: MFCD00143911 PubChem化学物质编号: 24873852 NACRES: NA.22
制造商品牌: 西格玛 Sigma-Aldrich
货号（SKU）: 515892
CAS号: 55120-75-7
MDL号: MFCD00143911
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说明

一般描述

Calcium trifluoromethanesulfonate, also known as calcium triflate [Ca(OTf)2], is widely employed as a Lewis acid catalyst in organic synthesis. It facilitates a range of reactions, including the aldol reaction, Michael additions, and ring-opening reactions of epoxides. In addition, it is also used as a reagent for the preparation of trifluoromethanesulfonate esters, which can be used as leaving groups in a range of organic transformations.
 

应用

Calcium trifluoromethanesulfonate can be used as a catalyst to synthesize β-amino alcohols via aminolysis of epoxides. It is also used in the one-pot conversion of aldehydes to their corresponding nitrile compounds.
 
 

属性

检测方案

99.9%

mp

350 °C (lit.)

SMILES string

[Ca++].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

InChI

1S/2CHF3O3S.Ca/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2

InChI key

PUQLFUHLKNBKQQ-UHFFFAOYSA-L

 

安全信息

储存分类代码

8B - Non-combustible, corrosive hazardous materials

WGK

WGK 3

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 30 | 欧洲Eur. ≥ 10 | 東京Tokyo ≥ 9 | 香港与北京 ≥ 30
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