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三(二甲胺基)膦,Tris(dimethylamino)phosphine [(Me2N)3P, HMPT];97%

别名:六甲基三氨基磷酸酯;六甲基三胺磷;六甲基亚磷酰三胺;(Me2N)3P, HMPT, Hexamethylphosphorous triamide, Hexamethyltriamidophosphite, Hexamethyltriaminophosphine

CAS号 1608-26-0 线性分子式 P[N(CH3)2]3 分子量 163.20 Beilstein/REAXYS Number 906778 MDL number MFCD00008301 PubChem Substance ID 24864511 NACRES NA.22
货号(SKU): 393290
CAS号: 1608-26-0
MDL号: MFCD00008301
增值税发票 √ 免费货运 [顺丰 联邦] √
HK$397.77

产品描述

Application

Tris(dimethylamino)phosphine can be used a reagent in combination with CCl4 for the conversion of hydroxyl groups to the corresponding chlorides; for hydroxyl group activation; dehydrations.

Tris(dimethylamino)phosphine can be used as a:
• Ligand in the preparation of arene-ruthenium(II) complex which is used as a catalyst in hydration of nitriles to amides.[1]
• Phosphorus source along with InCl3 in the synthesis of InP colloidal quantum dots (QDs).[2]
• Deoxygenating agent for some α-dicarbonyl compounds in the presence of fullerene C60.[3]

三(二甲基氨基)膦可与CCl4一起用作试剂,用于将羟基转化为相应的氯化物; 用于羟基活化; 脱水。

三(二甲基氨基)膦可用作:
•制备芳烃-钌(II)配合物时的配体,可将其用作腈水合成酰胺的催化剂。
•InP胶体量子点(QD)合成中的磷源与InCl3。
•在富勒烯C60存在下某些α-二羰基化合物的脱氧剂。

包装

5, 25 mL in glass bottle

性质

Quality Level100
assay97%
reaction suitabilityreagent type: ligand
reaction type: Reductions
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Wittig Reaction
refractive indexn20/D 1.463 (lit.)
bp48-50 °C/12 mmHg (lit.)
density0.898 g/mL at 25 °C (lit.)
functional groupphosphine
SMILES stringCN(C)P(N(C)C)N(C)C
InChI1S/C6H18N3P/c1-7(2)10(8(3)4)9(5)6/h1-6H3
InChI keyXVDBWWRIXBMVJV-UHFFFAOYSA-N


安全信息

符号
信号词 Danger
危害声明 H226 - H340 - H350
警示性声明 P201 - P210 - P308 + P313
危害码 (欧洲) T
风险声明 (欧洲) 45-46-10
安全声明 (欧洲) 53-45
RIDADR UN 1993C 3 / PGIII
WGK德国 WGK 3
RTECS TH3390000
商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 88 | 欧洲Eur. ≥ 126 | 東京Tokyo ≥ 46 | 香港与北京 ≥ 62