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一氯化碘,Iodine monochloride;ACS reagent, 1.10±0.1 I/Cl ratio basis

单氯化碘;Chloroiodide;CAS号 7790-99-0 线性分子式 ICl 分子量 162.36 EINECS 编号 232-236-7 MDL number MFCD00011354 PubChem Substance ID 329755974 NACRES NB.24
货号(SKU): 402990
CAS号: 7790-99-0
MDL号: MFCD00011354
增值税发票 √ 免费货运 [顺丰 联邦] √
HK$925.68

产品描述

一氯化碘是一种卤素间化合物。[9]它与乙基,异丙基和叔丁基苯形成各种络合物。已经评估了形成这些配合物的平衡常数。[6]通过溶解在极性溶剂中,可提供导电溶液。[7]它与胸苷,3-单-和3,3',5'-三烷基取代的胸苷的反应表明,它有助于胸苷的去糖基化,异构化和异构化。一氯化碘(ICl)可用于甲氧基和二甲氧基苯的卤化。[7]它可用于合成黄酮。[8]

一氯化碘可用于以下合成中:
•2-(4-卤代异喹啉-1-基)乙醇衍生物[2]
•5-碘水杨醛[3]
•5-芳基-6-碘-8-苯基吡唑并[1,5-c] -1,2,4-三唑并[4,3-a]嘧啶[4]
•(±)-1-环己基-4-碘-3-甲氧基丁烷-1-醇[5]
•(±)-4-碘-3--3-甲氧基-1-苯基丁-1-醇[5]

General description

Iodine monochloride is an interhalogen compound.[9] It forms various complexes with ethyl, isopropyl and t-butylbenzenes. Equilibrium constants for the formation of these complexes have been evaluated.[6] It affords electrically conducting solution on dissolution in polar solvents.[7] Its reaction with thymidine, 3-mono- and 3,3′,5′-trialkylsubstitued thymidine showed that it helps in deglycosylation, anomerization and isomerization of thymidine.[9]

Application

Iodine monochloride (ICl) may be employed for the halogenation of methoxy and dimethoxybenzenes.[7] It may be used for the synthesis of flavones.[8]

Iodine monochloride may be used in the synthesis of the following:
• 2-(4-haloisoquinolin-1-yl)ethanol derivatives[2]
• 5-iodosalicylaldehydes[3]
• 5-aryl-6-iodo-8-phenylpyrazolo[1,5-c]-1,2,4-triazolo[4,3-a]pyrimidines[4]
• (±)-1-cyclohexyl-4-iodo-3-methoxybutan-1-ol[5]
• (±)-4-Iodo-3-methoxy-1-phenylbutan-1-ol[5]

包装

25, 100 g in glass bottle

性质

Quality Level200
gradeACS reagent
assay1.10±0.1 I/Cl ratio basis
impurities≤0.005% insolubles
bp97.4 °C (lit.)
solubilityacetic acid: soluble(lit.)
acetone: soluble(lit.)
alcohol: soluble(lit.)
carbon disulfide: soluble(lit.)
density3.24 g/mL at 25 °C (lit.)
storage temp.2-8°C
SMILES stringClI
InChI1S/ClI/c1-2
InChI keyQZRGKCOWNLSUDK-UHFFFAOYSA-N


安全信息

符号
信号词
Danger
危害声明 H314 - H335
靶器官 Respiratory system
危害码 (欧洲) C
风险声明 (欧洲) 34-42
安全声明 (欧洲) 26-36/37/39-45
RIDADR UN 1792 8 / PGII
WGK德国 WGK 3
RTECS NN1650000
闪点(华氏) Not applicable
闪点(摄氏) Not applicable
商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 190 | 欧洲Eur. ≥ 66 | 東京Tokyo ≥ 82 | 香港与北京 ≥ 55
商品标签