Ammonium iron(II) sulfate hexahydrate can be used as a green catalyst in the:
- Newman-Kwart rearrangement to synthesize functionalized thiophenols.
- Oxidation of aromatic, aliphatic, and conjugated aldehydes to the corresponding carboxylic acids.
- Synthesis of biscoumarins via condensation reaction.
属性
reaction suitability
reagent type: catalyst
core: iron
杂质
≤0.01% insolubles
≤0.05% Not NH4OH pptd.
痕量阴离子
phosphate (PO43-): ≤0.003%
痕量阳离子
Ca: 0.005%
Cu: ≤0.003%
Fe3+: ≤0.01%
K: 0.002%
Mg: 0.002%
Mn: ≤0.01%
Na: 0.02%
Zn: ≤0.003%
SMILES string
N.N.O.O.O.O.O.O.[Fe++].OS([O-])(=O)=O.OS([O-])(=O)=O
InChI
1S/Fe.2H3N.2H2O4S.6H2O/c;;;2*1-5(2,3)4;;;;;;/h;2*1H3;2*(H2,1,2,3,4);6*1H2/q+2;;;;;;;;;;/p-2
InChI key
MQLVWQSVRZVNIP-UHFFFAOYSA-L
安全信息
储存分类代码
13 - Non Combustible Solids