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硝基苯,Nitrobenzene;ReagentPlus®, 99%

CAS号 98-95-3 经验分子式(希尔表示法) C6H5NO2 分子量 123.11 Beilstein/REAXYS Number 507540 EINECS 编号 202-716-0 MDL number MFCD00007043 PubChem Substance ID 329818483 NACRES NA.21
货号(SKU): N10950
CAS号: 98-95-3
MDL号: MFCD00007043
增值税发票 √ 免费货运 [顺丰 联邦] √
$149.53

产品描述

硝基苯是一种芳香族化合物,可以通过将苯与硝酸和硫酸的混合物硝化来制备。[1] 据报道,还原的氧化石墨烯催化的硝基苯还原可形成N-苯基羟胺作为中间体。[2] 烟草中的硝基苯引起DNA损伤的能力已通过单细胞凝胶电泳(SCGE)进行了评估。 硝基苯的光解机理已有报道。在钯二膦配合物的存在下,硝基苯可以用作甲醇氧化羰基化反应中的氧化剂。

General description

Nitrobenzene is an aromatic compound that can be prepared by the nitration of benzene with nitric acid and sulfuric acid mixture.[1] Reduced graphene oxide catalyzed reduction of nitrobenzene has been reported to form N-phenylhydroxylamine as an intermediate.[2] The ability of nitrobenzene to cause DNA damage has been assessed in tobacco by single-cell gel electrophoresis (SCGE). The mechanism of photolysis of nitrobenzene has been reported.[3]

Application

Nitrobenzene may be used as an oxidizing agent in the oxidative carbonylation of methanol in the presence of palladium diphosphane complexes.[4]

包装

1, 4 L in glass bottle

18 L in steel drum

法律信息

ReagentPlus 为以下机构的注册商标: Sigma-Aldrich Co. LLC

性质

Quality Level100
gradeReagentPlus®
vapor density4.2 (vs air)
vapor pressure0.15 mmHg ( 20 °C)
50 mmHg ( 120 °C)
assay99%
autoignition temp.899 °F
expl. lim.40 %
refractive indexn20/D 1.551 (lit.)
bp210-211 °C (lit.)
mp5-6 °C (lit.)
density1.196 g/mL at 25 °C (lit.)
SMILES string[O-][N+](=O)c1ccccc1
InChI1S/C6H5NO2/c8-7(9)6-4-2-1-3-5-6/h1-5H
InChI keyLQNUZADURLCDLV-UHFFFAOYSA-N


安全信息

符号
信号词
Danger
靶器官 Blood
危害码 (欧洲) T
风险声明 (欧洲) 60-23/24/25-40-48/23/24/25-52/53
安全声明 (欧洲) 53-45
RIDADR UN 1662 6.1 / PGII
WGK德国 WGK 3
RTECS DA6475000
闪点(华氏) 190.4 °F - closed cup
闪点(摄氏) 88.0 °C - closed cup
商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 190 | 欧洲Eur. ≥ 66 | 東京Tokyo ≥ 82 | 香港与北京 ≥ 55
商品标签